Guests for the evening also include Sen. Elizabeth Warren and founder of the Global Poverty Project, Hugh Evans, with a musical performance by Pearl Jam.
The CBS talk show airs weeknights beginning at 11:35 PM ET.
Guests for the current week follow:
Sept. 24: Author Andrew Sullivan; Journalist and Activist Maria Shriver; Comedian Jim Gaffigan; Archbishop Thomas Wenski
Sept. 25: Nobel Prize Laureate Malala Yousafzai; Actress Kerry Washington; musical performance by The Arcs