The popular artist will also take part in a sing-off with host Couric; Michael Feinstein will be featured at the piano.
Jackman, who was seen on screen in "X-Men Origins: Wolverine," earned a Tony Award for his work in the Broadway musical The Boy From Oz. He is also known for his film roles in the "X-Men" trilogy, "Someone Like You," "Swordfish," "Kate and Leopold," "Van Helsing," "The Fountain" and "Happy Feet" (in voice). His stage credits also include Hugh Jackman, Back on Broadway, Trevor Nunn's staging of Oklahoma! at Britian's National Theatre and award-winning work in productions of Sunset Boulevard and Beauty and the Beast in his homeland.
For more information visit www.katiecouric.com/station-finder.
For a sneak peek of the upcoming sing-off, click below.