In "The Movie Star," according to NBC, " Bombshell is turned upside-down by the arrival of movie star Rebecca Duvall (Thurman). Karen ( Katharine McPhee) and Ivy ( Megan Hilty) are drawn into an uneasy alliance against their new rival – but can they overcome their history? The romance between Tom ( Christian Borle) and Sam (Leslie Odom, Jr.) heats up, while Julia ( Debra Messing) and Frank ( Brian d'Arcy James) must put aside their differences to address a family crisis. Dev (Raza Jaffrey) faces a big decision." The episode also featured Anjelica Huston and Jack Davenport.
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To check out Thurman on "Smash," look below: