Guests that evening will also include Sen. Elizabeth Warren and founder of the Global Poverty Project, Hugh Evans, with a musical performance by Pearl Jam.

The CBS talk show airs weeknights beginning at 11:35 PM ET.

Guests for the upcoming week follow:

Sept. 21: NBA MVP Steph Curry; Senator Ted Cruz
Sept. 22: Donald Trump; U.S. Secretary of Energy Dr. Ernest Moniz; musical performance by Raury
Sept. 23: Actor Hugh Jackman and founder of the Global Poverty Project Hugh Evans; Senator Elizabeth Warren; musical performance by Pearl Jam
Sept. 24: Author Andrew Sullivan; Journalist and Activist Maria Shriver; Comedian Jim Gaffigan; Archbishop Thomas Wenski
Sept. 25: Nobel Prize Laureate Malala Yousafzai; Actress Kerry Washington; musical performance by The Arcs

As previously reported, the cast of An American in Paris will perform on the new late-night show Sept. 18.